207 research outputs found

    ADEPOS: Anomaly Detection based Power Saving for Predictive Maintenance using Edge Computing

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    In industry 4.0, predictive maintenance(PM) is one of the most important applications pertaining to the Internet of Things(IoT). Machine learning is used to predict the possible failure of a machine before the actual event occurs. However, the main challenges in PM are (a) lack of enough data from failing machines, and (b) paucity of power and bandwidth to transmit sensor data to cloud throughout the lifetime of the machine. Alternatively, edge computing approaches reduce data transmission and consume low energy. In this paper, we propose Anomaly Detection based Power Saving(ADEPOS) scheme using approximate computing through the lifetime of the machine. In the beginning of the machines life, low accuracy computations are used when the machine is healthy. However, on the detection of anomalies, as time progresses, the system is switched to higher accuracy modes. We show using the NASA bearing dataset that using ADEPOS, we need 8.8X less neurons on average and based on post-layout results, the resultant energy savings are 6.4 to 6.65XComment: Submitted to ASP-DAC 2019, Japa

    A simple thermodynamical witness showing universality of macroscopic entanglement

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    We show that if the ground state entanglement exceeds the total entropy of a given system, then this system is in an entangled state. This is a universal entanglement witness that applies to any physical system and yields a temperature below which we are certain to find some entanglement. Our witness is then applied to generic bosonic and fermionic many body systems to derive the corresponding "critical" temperatures that have a very broad validity.Comment: 3 pages, Torun conference, June 25-28, 200

    Role of the hydrophobic effect in the transfer of chirality from molecules to complex systems. From chiral surfactants to porphyrin/surfactant aggregates

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    The interaction between the achiral sulfonated porphyrin 5,10,15,20-tetrakis(4-sulfonatophenyl) porphyrin, H2TPPS4, and two chiral cationic surfactants has been studied by optical absorption, fluorescence, and circular dichroism (CD) spectroscopies. At surfactant concentrations above the critical micellar concentration (cmc) the porphyrin is included in the micellar aggregates, but it is CD silent. Below the cmc at a definite porphyrin/surfactant stoichiometry the formation of heteroaggregates with transfer of chirality to the porphyrin chromophore occurs. The preferred surfactant/porphyrin stoichiometry is 3:1, which suggests a structure driven by electrostatic and hydrophobic interactions between porphyrin and surfactant and dipolar and ionic interactions with the water solution. At surfactant concentrations above the cmc, depending on the protocol of preparation of the samples, the formation of the two kinds of aggregates can be observed, reversible for the simple surfactant micelles incorporating the porphyrin, but irreversible for the heteroaggregates

    Case history of porphyrin J-aggregates: a personal point of view

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    The formation and structure of the title aggregates are paradigms of the self-assembly of amphiphilic molecular building blocks in supramolecular chemistry. This review summarizes the research in the University of Barcelona on the homoassociation of the water soluble meso 4-sulfonatophenyl-and phenyl substituted porphyrins

    A Wall Effects and Means of Controlling the Evolution of Swirling Flows with Vortex Breakdown

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    This paper investigates numerically the bubble-type vortex breakdown apparition in the case of closed rotating flows of a viscous, axisymmetric, and incompressible fluid. First, a truncated conical/cylindrical cavity of spherical end disks is used to simulate and analyze the vortex structure under rigid surface conditions. The geometric effects of the enclosure are also studied. Vortex breakdown is demonstrated beyond the lower disk rotation rate threshold by introducing the no-slip condition imposed on the upper wall. The objective is to explore ways of controlling the evolution of this physical event by modifying the confinement conditions upstream of the vortex rupture. Particular attention is also paid to the effective kinematic viscosity, thermal diffusivity and geometric control of recirculation zones on the axis of rotation (axial bubble type). The second geometry consists of a spherical annulus formed by two concentric hemispheres in differential rotation under plat-free surface conditions. The results show that rotation of the inner hemisphere induces a vortex bubble on the polar axis. In contrast, the outer hemisphere rotation induces a toroidal vortex on the equator

    Diastereoisomerism, Stability, and Morphology of Substituted meso-4-Sulfonatophenylporphyrin J-Aggregates

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    The comparison between nanoparticle morphologies of the J-aggregates of different meso-4-sulfonatophenylporphyrins showing non-sulfonato groups at some of the meso-positions constitutes an ultimate proof of the 2D crystal-like character of the basic self-assembly motif of this family of J-aggregates. Diastereoisomerism stemming from the tacticity of the relative configurations in relation to the J-aggregate bidimensional sheet is the key factor that determines both the striking monolayer in solution and also the hierarchical pathways leading to different nanoparticle morphologies upon further growth. The unexpected stability of such large monolayered sheets made up of porphyrin units is probably caused by the support originated at both surface faces by the double layer potentials of the peripheral ionic substituents. These double layer potentials play a driving role in the subsequent 3D growth of the monolayers, as deduced herein from the determining role of tacticity both in the stability of the J-aggregate sheet and in its evolution either to monolayered or to bilayered nanoparticles. The stabilizing role of the forces at the electrical double layer of the particle suggests a relationship between these forces and the previously reported detection of racemic biases when shear hydrodynamic forces are in action during the aggregation process

    Formation of an epitaxial monolayer on graphite upon short-time surface contact with highly diluted aqueous solutions of 1-monostearoylglycerol

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    Short-time surface contact of highly diluted 1-monostearoylglycerol (1-MSG) aqueous solutions with highly oriented pyrolitic graphite results in the deposition of an epitaxial monolayer that can be detected by atomic force microscopy operating in tapping mode at the graphite-air interface. The monolayer obtained with the racemic mixture is then compared to that obtained with one of the pure enantiomers. The analogous behavior found for aqueous solutions of rac-1-MSG and 3-sn-MSG implies a two-dimensional self-assembly process with chiral discrimination. The results suggest that the monolayer originates from species located at the surface of the deposition drop. They also indicate that the simple experimental procedure reported, or more elaborate Langmuir-Schaefer methods, could be the method of choice to prepare other monolayers of similar surfactants
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